In case anyone is interested Amazon UK [[not sure about other territories sorry, I'm UK based) are selling MP3 files of some Motown performances from various Ed Sullivan shows.
For example:
Come see about me - The Supremes
Stand/Who's lovin' you/I want you back - The Jackson 5
I'm gonna make you love me - The Temptations
I stumbled across them searching for Jackson 5 songs [[and didn't realise you could buy their performances as a medley until after purchasing all three songs separately)
I searched "Live on the ed sullivan show" in digital music to bring more results up.
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